31 research outputs found

    Thermodynamics of entropy-driven phase transformations

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    Thermodynamic properties of one-dimensional lattice models exhibiting entropy-driven phase transformations are discussed in quantum and classical regimes. Motivated by the multistability of compounds exhibiting photoinduced phase transitions, we consider systems with asymmetric, double, and triple well on-site potential. One finds that among a variety of regimes, quantum versus classical, discrete versus continuum, a key feature is asymmetry distinguished as a "shift" type and "shape" type in limiting cases. The behavior of the specific heat indicates one phase transformation in a "shift" type and a sequence of two phase transformations in "shape"-type systems. Future analysis in higher dimensions should allow us to identify which of these entropy-driven phase transformations would evolve into phase transitions of the first order

    Domain h Type Collective Dimerization of Graphite and Possible sp2sp^2 rightarrow sp3sp^3 Transition Induced by Inter h Layer Charge Transfer Excitations in the Visible Region

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    We theoretically study possible domain-type collective dimerizations of graphite induced by inter-layer charge transfer excitations in the visible region. Using the semiempirical Brenner theory, we have calculated the adiabatic energy along the path that starts from original two distant graphite layers, but finally reaches the dimerized domain which consists of about 100 carbons with inter-layer σ-bonds. The energy barrier between this new domain and the starting graphite is shown to be of the order of 1 eV, being easily overcome by applying a few visible photons. We have also shown the optimal path of transformation via step by step increase of the domain size

    How Nodes and Groups Properties Influence Assortativity in Social Networks?

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    A model of social network construction taking into account both social and individual influences on the distribution of links is proposed. The balance between social and individual factors is regulated through a "flexibility" parameter, reflecting how strong the initial individual sociability is altered by groups structure. The main interest is focused on the effect of groups on degree-degree correlation. Both numerical and analytical results on the relationship between assortativity and flexibility are presented

    An attempt to assess the effect of tourist trail width on adjacent forest environment

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    The impact of narrow (up to 2 m), medium (up to 3.5 m) and wide (>3.5 m) tourist trails on the surrounding environment was investigated. On wide trails, the value of soil erosion and compaction indices was found to be the highest, while the herb height index was the lowest indicating the greatest impact of wide trails on the environment. The phytosociological relevés were used to determine ecological indicator figures. Wide trails were characterized by higher thermal and continentalism indices and lower pH and trophic indices. The proportion of therophytes and geophytes was higher, while of hemicryptophytes, phanerophytes and chamaephytes on wide trails were lower than on medium and narrow trails. All the analysed indices pointed to a stronger impact of wide trails on the environment in comparison with medium and narrow trails
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